Womic Stainless Steel Co., Ltd
Exceptional Pitting and Crevice Corrosion Resistance: PRE ≥ 42 (typically 42–45) due to high chromium (24–26%), high molybdenum (3.0–5.0%), and nitrogen (0.24–0.32%) content – the highest among duplex stainless steels for lined pipe applications.
Ultra-High Mechanical Strength: Minimum yield strength of lining ≥ 550 MPa (approximately 3.2 times that of 316L and 1.2 times that of Duplex 2205).
Superior Chloride SCC Resistance: Excellent resistance to chloride-induced stress corrosion cracking, significantly outperforming both austenitic grades and standard duplex 2205.
NACE MR0175 / ISO 15156 Compliant: Fully qualified for extreme sour service with highest allowable H₂S partial pressures and lowest pH values.
Excellent Low-Temperature Toughness: Lining maintains excellent impact toughness down to -50°C with Charpy V-Notch ≥ 70J typical at -46°C.
Cost-Effective Alternative to Solid Super Duplex: Reduces material cost by 60-80% compared to solid Super Duplex 2507 pipe while providing equivalent internal corrosion protection.
High Resistance to Erosion and Corrosion Fatigue: Super Duplex lining provides outstanding resistance to high-velocity seawater and abrasive slurry applications.
Good Weldability: Requires strict procedure with low heat input, N₂ shielding gas, and ER2594 filler metal for overlay.
Weldable End Preparation: Available with weld overlay transition (butter layer) using ER2594 filler metal at pipe ends for field welding.
Full Range of Sizes: Available from 2″ to 48″ (DN50 to DN1200) with lining thickness from 2mm to 8mm.
International Certifications: Lined pipes can be certified by ABS, BV, DNV, LR, GL, RINA, CCS, KR, and NK, and comply with NORSOK M-630, NACE MR0175, API 5LC, and ISO 13628-4 standards.
|
Standard |
Description |
Base Pipe Grade |
Lining Grade |
|
API 5L |
Line pipe for oil and gas |
Gr B, X52, X60, X65, X70 |
S32750 |
|
ASTM A694 |
High-yield carbon steel pipe fittings (base pipe) |
F52, F60, F65 |
S32750 |
|
ASTM A333 |
Low-temperature carbon steel pipe |
Grade 6 |
S32750 |
|
ASTM A106 |
Seamless carbon steel pipe |
Grade B |
S32750 |
|
ASME B31.3 |
Process piping |
Various |
S32750 |
|
ASME B31.4 |
Pipeline transportation systems |
Various |
S32750 |
|
ASME B31.8 |
Gas transmission and distribution piping |
Various |
S32750 |
|
API 5LC |
CRA line pipe |
Various |
S32750 |
|
DNV-OS-F101 |
Submarine pipeline systems |
Various |
S32750 |
|
NORSOK M-630 |
Offshore material standard |
Various |
Grade 2507 |
|
NACE MR0175 / ISO 15156 |
Sour service compliance (highest allowable limits) |
Various (hardness controlled) |
S32750 |
|
ISO 13628-4 |
Subsea production systems |
Various |
S32750 |
|
Element |
C |
Mn |
P |
S |
Si |
Cr |
Ni |
Mo |
N |
Cu |
|
S32750 |
≤0.030 |
≤1.20 |
≤0.035 |
≤0.020 |
≤0.80 |
24.0–26.0 |
6.0–8.0 |
3.0–5.0 |
0.24–0.32 |
≤0.50 |
Super Duplex 2507 (S32750) contains higher chromium, molybdenum, and nitrogen compared to Duplex 2205, resulting in a PRE value of ≥42 (compared to ≤35 for 2205). PREN = %Cr + 3.3 × %Mo + 16 × %N ≥ 42 (typically 42–45).
Comparison of PRE (Pitting Resistance Equivalent) Values:
|
Lining Grade |
PRE |
Seawater Suitability |
Sour Gas Suitability |
H₂S Partial Pressure Tolerance |
|
316/316L |
24-26 |
Limited |
Poor |
Low |
|
Duplex 2205 |
34-35 |
Good |
Good |
Moderate |
|
Super Duplex 2507 |
42-45 |
Excellent |
Excellent |
Highest |
|
Component |
Material |
Tensile Strength (MPa) |
Yield Strength (MPa) |
Elongation (%) |
|
Base Pipe (API 5L X65) |
Carbon Steel |
≥535 |
≥450 |
≥18 |
|
Base Pipe (API 5L X70) |
Carbon Steel |
≥570 |
≥485 |
≥17 |
|
Base Pipe (A694 F65) |
High-Yield CS |
≥530 |
≥450 |
≥20 |
|
Base Pipe (A333 Gr 6) |
Low-Temp CS |
≥415 |
≥240 |
≥22 |
|
Lining (Super Duplex 2507) |
Super Duplex |
≥800 |
≥550 |
≥25 |
|
Lining (Ferrite Controlled) |
Super Duplex |
≥800 |
≥550 |
≥25 |
|
Parameter |
Seamless Base Pipe |
Welded (SAW) Base Pipe |
|
Pipe Size Range |
2″ – 24″ (DN50 – DN600) |
8″ – 48″ (DN200 – DN1200) |
|
Base Pipe Wall Thickness |
Sch 40 – Sch 160 |
Sch 20 – Sch 80 |
|
Lining Thickness |
2mm – 8mm |
2mm – 8mm |
|
Standard Lengths |
6m, 12m |
6m, 12m |
|
End Preparation |
Beveled, Weld Overlay |
Beveled, Weld Overlay |
|
Base Pipe Grades |
API 5L X52-X70, A106 Gr B, A333 Gr 6, A694 F52-F65 |
API 5L X52-X70, A53 Gr B |
|
Service Severity |
Lining Thickness (mm) |
Recommended for |
|
Deepwater Subsea (3000m) |
2.5mm – 4.0mm |
Subsea manifolds, flowlines |
|
HP/HT Sour Gas |
3.0mm – 5.0mm |
High H₂S, high pressure gas |
|
Extreme Seawater (High Velocity) |
3.5mm – 5.0mm |
Seawater injection, lift systems |
|
H₂S/CO₂ Mixed Service |
4.0mm – 6.0mm |
Severe sour service |
|
Deepwater Riser Systems |
5.0mm – 8.0mm |
Dynamic risers, SCR |
|
Arctic/Cold Climate Subsea |
4.0mm – 6.0mm |
Low-temperature subsea |
Base Pipe Selection: High-quality carbon steel, high-yield steel, or low-temperature steel base pipe selected based on service pressure, temperature, and depth requirements.
Base Pipe Preparation: Base pipe is cleaned (shot blasting to SA 2.5), inspected for surface defects, and prepared for lining application.
Lining Tube Fabrication: Super Duplex 2507 stainless steel sheet is rolled and welded into a tube slightly smaller than the base pipe ID using ER2594 filler metal.
Lining Insertion: The Super Duplex 2507 lining tube is inserted into the base pipe.
Hydraulic Expansion: High-pressure water (up to 5000 psi) expands the lining tube against the base pipe inner wall, creating a tight mechanical bond with controlled ferrite content (35-65%).
Ferrite Content Verification: Lining material verified to have 35–65% ferrite content (minimum 40% for sour service) – documented.
Microstructure Examination: Verification of balanced dual-phase structure, absence of intermetallic phases (sigma, chi).
Weld Overlay (Butter Layer): Pipe ends are prepared with Super Duplex 2507 weld overlay using ER2594 filler metal with N₂ shielding gas.
Hydrostatic Testing: Each lined pipe is hydrostatically tested to 1.5× design pressure to verify bond integrity.
NDT Inspection: Ultrasonic testing (UT), eddy current testing (ECT), and ferrite measurement verify lining thickness, bond quality, and phase balance – 100% coverage.
Charpy Impact Testing: For low-temperature service at -46°C (upon request).
End Finishing: Pipe ends are beveled per ASME B16.25 and prepared for field welding.
Marking & Coating: Pipes are marked with grade, size, lining thickness, heat number, ferrite content, and standard. External coating (FBE, 3LPE, 3LPP, concrete weight coating) applied upon request.
|
Parameter |
Requirement |
|
Weld Overlay Material |
ER2594 |
|
Overlay Thickness |
4mm – 6mm (minimum) |
|
Overlay Length |
50mm – 100mm from pipe end |
|
Overlay Application |
GTAW (TIG) or GMAW (MIG) with N₂ shielding gas (3-5% N₂) |
|
Interpass Temperature |
≤150°C |
|
Ferrite Content of Overlay |
35-65% |
|
Heat Treatment |
Not required (PWHT not necessary for Super Duplex) |
|
Preheating |
100-150°C for carbon steel base |
|
Shielding Gas |
Ar + 3-5% N₂ (critical) |
Base Pipe Inspection: Chemical analysis, mechanical testing, dimensional check, hardness test, NDE per API 5L/A106/A333.
Lining Material Verification: PMI 100% for Super Duplex 2507 lining material – verification of Cr (24-26%), Ni (6-8%), Mo (3-5%), N (0.24-0.32%).
Ferrite Content Measurement: 35–65% ferrite required (minimum 40% for sour service) – documented per heat.
Microstructure Examination: Verification of balanced dual-phase structure, absence of intermetallic phases (sigma, chi) – per NORSOK M-630.
Bond Integrity Testing: Ultrasonic test (UT) to verify bond between lining and base pipe – 100% coverage.
Lining Thickness Check: Ultrasonic thickness measurement at multiple points (minimum 4 points per meter).
Hydrostatic Test: Each pipe tested at 1.5× design pressure (minimum 1.5× MAWP) – documented.
Hardness Testing: ≤32 HRC for lining (NACE compliance).
Charpy Impact Testing: -46°C (-50°F) for offshore projects (upon request) – ≥70J typical.
Pitting Corrosion Test: ASTM G48 Method A – no pitting at 40°C (or 50°C for NORSOK) – upon request.
Sour Service Qualification (upon request): HIC per NACE TM0284, SSC per NACE TM0177.
Third-Party Inspection: SGS, BV, DNV, TUV, LR, ABS available.
Deepwater Subsea Oil & Gas: Subsea flowlines, riser systems, pipeline end termination (PLET) jumpers, subsea manifold headers, deepwater export lines (ISO 13628-4 compliant, ABS/BV/DNV certified to 3000m water depth).
HP/HT Sour Gas Pipelines: High-pressure, high-temperature sour gas gathering lines, wellhead flowlines, HP gas export pipelines (NACE MR0175 compliant, highest H₂S limits).
Offshore Platforms (Critical Service): Topsides HP/HT process piping, riser caissons, produced water lines, HP chemical injection lines (NORSOK M-630 certified).
Seawater Systems (High Velocity): High-pressure seawater injection lines, deepwater seawater lift risers, firewater system headers.
Desalination Plants (High Temperature): High-pressure brine lines, reverse osmosis feed headers, energy recovery device connections.
Flue Gas Desulfurization (FGD): Absorber recirculation lines, slurry headers, quench water lines – for high-chloride, low-pH zones.
Hydrometallurgy: Pressure acid leaching (PAL) feed lines, high-temperature solvent extraction transfer lines.
Geothermal Energy: High-temperature, high-chloride, high-H₂S brine flowlines, steam condensate return lines.
Military/Naval (Critical Systems): Naval vessel seawater systems, submarine ballast discharge lines, degaussing system piping (classification society certified).
|
Pipe Type |
6″ Sch 40 |
12″ Sch 40 |
24″ Sch 30 |
36″ Sch 20 |
|
Solid Super Duplex 2507 Pipe |
100% (baseline) |
100% (baseline) |
100% (baseline) |
100% (baseline) |
|
Lined Pipe (CS + 4mm Super Duplex) |
20-30% |
15-25% |
10-20% |
8-15% |
|
Cost Savings |
70-80% |
75-85% |
80-90% |
85-92% |
|
Requirement |
Super Duplex 2507 Lined Pipe Compliance |
|
Lining Material |
S32750 (PRE ≥42) – Fully Compliant – Highest Limits |
|
Base Pipe Hardness |
≤22 HRC (carbon steel) – Controlled |
|
Weld Overlay (Butter) |
ER2594 – Hardness ≤32 HRC |
|
H₂S Partial Pressure |
Up to 20 psia (highest for duplex, consult NACE) |
|
Maximum Temperature |
232°C (450°F) |
|
pH Range |
3.5 – 6.5 (depending on H₂S partial pressure) |
|
HIC Test (NACE TM0284) |
Available upon request |
|
SSC Test (NACE TM0177) |
Available upon request |
1. Why choose Super Duplex 2507 lined pipe instead of solid
Super Duplex 2507?
Super Duplex 2507 lined pipe provides the same internal corrosion resistance as
solid Super Duplex at 15-25% of the material cost for large diameters. The
carbon steel or high-yield steel base pipe provides structural strength at much
lower cost, making it an economical choice for deepwater subsea flowlines,
HP/HT sour gas pipelines, and long-distance offshore applications. Cost savings
of 75-90% can be achieved, especially for large-diameter pipelines.
2. What is the maximum water depth for Super Duplex 2507
lined pipes?
With appropriate base pipe (API 5L X65/X70 with high collapse resistance) and
external coating, Super Duplex 2507 lined pipes are suitable for water depths
up to 3000 meters (10,000 feet) for subsea applications. DNV-OS-F101 compliance
documentation available.
3. Can Super Duplex 2507 lined pipes be used for HP/HT sour service?
Yes. Super Duplex 2507 is fully NACE MR0175 / ISO 15156 compliant for sour service with the highest allowable H₂S partial pressures for duplex stainless steels. The combination of S32750 lining with appropriate high-yield base pipe (API 5L X65) provides excellent HP/HT sour gas performance.
4. What is the maximum service temperature for Super Duplex
2507 lined pipes?
250°C (482°F) for continuous service in chloride environments; 300°C (572°F)
for non-chloride service in the base pipe. The lining maintains its corrosion
resistance up to 250°C.
5. Can Super Duplex 2507 lined pipes be welded in the field?
Yes, with proper weld overlay (buttering) at pipe ends using ER2594 filler
metal and N₂ shielding gas (Ar + 3-5% N₂). The multilayer weld overlay provides
a transition layer allowing welding between carbon steel base pipes while
maintaining corrosion resistance and ferrite phase balance (35-65% ferrite) at
the weld joint. Qualified welding procedures (WPS/PQR) are available.
6. What base pipe material is recommended for deepwater
subsea applications?
API 5L X65 or X70 with enhanced collapse resistance (as per DNV-OS-F101) is
recommended for deepwater subsea applications. Grade X65 provides good strength
and weldability; Grade X70 offers higher strength for deeper water
applications.
7. What base pipe material is recommended for low-temperature
service (-46°C)?
ASTM A333 Grade 6 is recommended for low-temperature service down to -46°C
(-50°F). Charpy impact testing at -46°C can be provided for both base pipe and
lining upon request.
8. What is the minimum lining thickness for deepwater HP/HT
sour gas service?
Minimum 4mm Super Duplex 2507 lining for deepwater HP/HT sour gas service. For
severe sour service (high H₂S, low pH), 5-6mm lining thickness is recommended
to provide additional corrosion allowance.
Highest Corrosion Resistance: PRE ≥42 – highest among duplex stainless steels for lined pipe applications
Deepwater Subsea Certified: ABS, BV, DNV, LR certified for water depths up to 3000m
NACE MR0175 / ISO 15156 Compliant: Highest H₂S partial pressure tolerance for sour service
NORSOK M-630 Qualified: Complete offshore and subsea documentation packages
DNV-OS-F101 Compliant: Suitable for submarine pipeline systems
ISO 13628-4 Compliant: Suitable for subsea production systems
Ferrite Controlled: 35-65% ferrite documented (minimum 40% for sour service)
Charpy Impact Tested: -46°C (-50°F) documented for offshore projects
ASTM G48 Corrosion Tested: Pitting resistance verified
API 5LC Compliant: CRA line pipe for oil and gas
Full Traceability: Heat number on each pipe – traceable to original mill certificate
Complete Size Range: 2″ to 48″ (DN50 to DN1200) – standard and custom sizes
Multiple Base Pipe Grades: API 5L X52-X70, A694 F52-F65, A333 Gr 6, A106 Gr B
Lining Thickness Options: 2mm to 8mm – tailored to your service severity
Weld Overlay Ready: Pipe ends prepared with ER2594 butter layer for field welding
Third-Party Inspection: SGS, BV, DNV, TUV, LR, ABS available
Global Delivery: Exported to major deepwater subsea, HP/HT sour gas, and extreme offshore projects worldwide (Gulf of Mexico, North Sea, Brazil Santos Basin, West Africa, SE Asia)
Website: www.womicstainless.com
E-mail: info@womicstainless.com
Tel / WhatsApp / WeChat:
Victor: +86 15575100681
Jack: +86 18390957568
Womic Steel – Your reliable partner for high quality stainless steel products, precision machined components, and custom solutions for corrosion resistant applications.
Stock Examples (Super Duplex 2507 Lined Pipes – API 5L X65 Base – 4mm Lining – Weld Overlay Ends – NACE MR0175 – Deepwater Subsea):
|
NPS |
DN |
Base Pipe Schedule |
Lining Thickness |
Base Pipe Grade |
Typical Application |
Water Depth |
|
4″ |
100 |
Sch 80 |
4mm |
API 5L X65 |
Subsea chemical injection |
3000m |
|
6″ |
150 |
Sch 80 |
4mm |
API 5L X65 |
Subsea manifold flowlines |
3000m |
|
8″ |
200 |
Sch 60 |
4mm |
API 5L X65 |
HP/HT sour gas gathering |
2500m |
|
10″ |
250 |
Sch 60 |
5mm |
API 5L X65 |
Deepwater export lines |
2000m |
|
12″ |
300 |
Sch 40 |
5mm |
API 5L X70 |
Subsea riser systems |
3000m |
|
16″ |
400 |
Sch 40 |
6mm |
API 5L X70 |
PLET jumper flowlines |
2500m |
|
20″ |
500 |
Sch 30 |
6mm |
API 5L X70 |
Deepwater trunk lines |
2000m |
|
24″ |
600 |
Sch 30 |
6mm |
API 5L X70 |
Offshore export pipelines |
1500m |
|
30″ |
750 |
Sch 20 |
8mm |
API 5L X70 |
Major subsea pipelines |
1000m |
|
36″ |
900 |
Sch 20 |
8mm |
API 5L X70 |
Deepwater gas export |
1000m |
|
42″ |
1050 |
Sch 20 |
8mm |
API 5L X70 |
Ultra-deepwater |
800m |
|
48″ |
1200 |
Sch 20 |
8mm |
API 5L X70 |
Deepwater trunklines |
800m |
Stock Examples (Super Duplex 2507 Lined Pipes – A694 F65 Base – High Pressure – 5mm Lining – HP/HT Sour Service):
|
NPS |
DN |
Base Pipe WT |
Lining Thickness |
Base Pipe Grade |
Typical Application |
Pressure Rating |
|
4″ |
100 |
12.7mm |
5mm |
A694 F65 |
HP/HT wellhead flowlines |
5000 psi |
|
6″ |
150 |
15.9mm |
5mm |
A694 F65 |
Choke manifold connections |
5000 psi |
|
8″ |
200 |
19.1mm |
6mm |
A694 F65 |
HP gas export headers |
5000 psi |
Stock Examples (Super Duplex 2507 Lined Pipes – A333 Gr 6 Base – Low Temperature – Arctic Service – 4mm Lining):
|
NPS |
DN |
Base Pipe Schedule |
Lining Thickness |
Base Pipe Grade |
Typical Application |
Temperature |
|
6″ |
150 |
Sch 80 |
4mm |
A333 Gr 6 |
Arctic sour gas gathering |
-46°C |
|
8″ |
200 |
Sch 80 |
4mm |
A333 Gr 6 |
Low-temperature subsea |
-46°C |
|
10″ |
250 |
Sch 60 |
5mm |
A333 Gr 6 |
Arctic offshore pipelines |
-46°C |
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