Womic Stainless Steel Co., Ltd
Premier Hydrofluoric Acid (HF) Resistance: Standard material for HF alkylation service, handling HF across all concentrations up to 150°C (302°F), making Monel 400 the preferred plate material for refinery HF storage tanks and process vessels.
Exceptional Seawater Erosion Resistance: Handles velocities up to 10 m/s (33 ft/s) without impingement attack – significantly outperforms 316L, duplex, and titanium in high-velocity seawater applications.
Excellent Chloride SCC Resistance: High nickel content (≥63%) provides outstanding resistance to chloride-induced SCC, outperforming all austenitic stainless steel grades.
Superior Biofouling Resistance: Naturally resists marine biofouling, reducing maintenance requirements and preserving flow efficiency in seawater systems.
Non-Magnetic Properties: Low magnetic permeability (<1.005) for degaussing systems on naval vessels and sensitive instrumentation applications.
Good Resistance to Reducing Acids: Excellent performance in deaerated sulfuric acid, hydrochloric acid, phosphoric acid, and organic acids.
Good High-Temperature Strength: Maintains excellent mechanical properties up to 400°C (752°F) in non-oxidizing environments.
Good Weldability: Nickel-copper alloy offers good weldability with matching filler metals (ERNiCu-7). Weld zones retain corrosion resistance comparable to the base metal.
International Certifications: Plates can be certified by ABS, BV, DNV, LR, GL, RINA, CCS, KR, and NK for marine and shipbuilding applications, and comply with NACE MR0175 (limited sour service) and ASME standards.
|
Standard |
Description |
Corresponding Monel 400 Grade |
|
ASTM B127 |
Standard specification for nickel-copper alloy plate, sheet, and strip |
UNS N04400 |
|
ASTM B906 |
General requirements for nickel alloy plate, sheet, and strip |
UNS N04400 |
|
ASME SB127 |
ASME specification for nickel-copper alloy plate |
UNS N04400 |
|
EN 10028-7 |
European standard for stainless steel flat products for pressure purposes |
2.4360 (NiCu30Fe) |
|
EN 10088-2 |
European standard for stainless steel sheet/plate for general purposes |
2.4360 |
|
EN 10088-4 |
European standard for stainless steel sheet/plate for structural purposes |
2.4360 |
|
JIS G4304 |
Japanese standard for hot-rolled stainless steel plate, sheet, and strip |
NW4400 |
|
JIS G4305 |
Japanese standard for cold-rolled stainless steel plate, sheet, and strip |
NW4400 |
|
GB/T 4237 |
Chinese standard for hot-rolled stainless steel plate, sheet, and strip |
N04400 |
|
NORSOK M-650 |
Offshore material qualification |
Monel 400 |
|
NACE MR0175 / ISO 15156 |
Sour service compliance (limited conditions) |
Monel 400 |
|
Element |
Ni |
Cu |
Fe |
C |
Mn |
P |
S |
Si |
Others |
|
Monel 400 |
≥63.0 |
28.0–34.0 |
≤2.5 |
≤0.30 |
≤2.0 |
≤0.024 |
≤0.024 |
≤0.50 |
— |
Monel 400 (UNS N04400) is a nickel-copper alloy with high nickel (≥63%) and copper (28-34%) content. The high nickel content provides excellent resistance to chloride stress corrosion cracking and caustic environments, while the copper content provides outstanding resistance to hydrofluoric acid, seawater biofouling, and reducing acids. Unlike precipitation-hardenable nickel alloys, Monel 400 is a solid solution strengthened alloy with no intentional precipitation hardening additions, making it exceptionally stable in marine environments and HF service.
Comparison of Seawater and Chemical Performance:
|
Grade |
Nickel (%) |
Copper (%) |
Seawater Erosion Resistance |
HF Acid Resistance |
Chloride SCC |
Non-Magnetic |
|
316L Stainless |
10-14 |
— |
Fair |
Poor |
Poor |
No |
|
Duplex 2205 |
4.5-6.5 |
— |
Good |
Poor |
Excellent |
No |
|
Super Duplex 2507 |
6-8 |
— |
Excellent |
Poor |
Excellent |
No |
|
Alloy 825 |
38-46 |
1.5-3.0 |
Good |
Fair |
Excellent |
No |
|
Alloy 625 |
≥58 |
— |
Outstanding |
Poor |
Outstanding |
No |
|
Monel 400 |
≥63 |
28-34 |
Excellent |
Excellent |
Excellent |
Yes |
|
Property |
Unit |
Monel 400 (Annealed) |
|
Tensile Strength |
MPa |
≥480 |
|
Yield Strength (0.2% offset) |
MPa |
≥170 |
|
Elongation |
% |
≥35 |
|
Hardness (Brinell) |
HBW |
≤180 |
|
Density |
g/cm³ |
8.80 |
|
Melting Range |
°C |
1300–1350 |
|
Thermal Conductivity (20°C) |
W/m·K |
21.8 |
|
Coefficient of Thermal Expansion (20–100°C) |
μm/m·K |
13.9 |
|
Modulus of Elasticity |
GPa |
179 |
|
Magnetic Permeability |
μ (at 200 Oe) |
<1.005 |
High-Temperature Tensile Properties (Typical Values):
|
Temperature (°C) |
Tensile Strength (MPa) |
Yield Strength (MPa) |
|
20 |
500–600 |
200–280 |
|
100 |
480–580 |
180–260 |
|
200 |
460–560 |
170–250 |
|
300 |
440–540 |
160–240 |
|
400 |
420–500 |
150–220 |
|
500 |
380–460 |
130–200 |
NACE MR0175 / ISO 15156 Compliance
(Limited Sour Service):
Monel 400 is compliant for sour service applications under specific conditions
as defined in NACE MR0175/ISO 15156. Maximum sour service temperature: 232°C
(450°F).
Maximum Recommended Service Temperatures:
|
Service Type |
Maximum Temperature |
|
Continuous Service (Seawater/Brine) |
260°C (500°F) |
|
Continuous Service (HF Acid) |
150°C (302°F) |
|
Continuous Service (Reducing Environment) |
400°C (752°F) |
|
Intermittent Service |
450°C (842°F) |
|
Minimum Service Temperature |
-196°C (-321°F) |
Critical Note: Monel 400 is not recommended for service in oxidizing acids (e.g., nitric acid, chromic acid) as it will experience rapid attack. It should also not be used in sulfur-containing environments at high temperatures (above 450°C) due to susceptibility to sulfur attack (sulfidation).
Heat Treatment Condition:
Monel 400 plates are normally supplied in the annealed condition (heat
treated at 700–800°C) followed by air cooling. This heat treatment relieves
internal stresses from rolling, restores optimum ductility and corrosion resistance,
and ensures a stable microstructure for marine and HF service.
Delivery Condition:
Plates are normally supplied in annealed and pickled condition,
providing a clean, smooth surface and excellent corrosion resistance. Upon
request, bright annealed finish can be provided for
high-purity applications.
|
Parameter |
Hot-Rolled Plates |
|
Thickness Range |
3mm – 60mm |
|
Width Range |
1500mm – 2500mm |
|
Length Range |
3000mm – 10000mm |
|
Surface Finish |
No.1 (Annealed & Pickled) |
|
Edge Condition |
Mill edge |
Thickness Tolerances (Hot-Rolled – ASTM A480):
|
Thickness (mm) |
Width ≤1500mm (mm) |
Width 1500-2000mm (mm) |
Width >2000mm (mm) |
|
3.0 – 5.0 |
±0.30 |
±0.35 |
±0.45 |
|
5.0 – 8.0 |
±0.35 |
±0.40 |
±0.50 |
|
8.0 – 12.0 |
±0.45 |
±0.50 |
±0.60 |
|
12.0 – 20.0 |
±0.60 |
±0.70 |
±0.80 |
|
20.0 – 35.0 |
±0.80 |
±0.90 |
±1.00 |
|
35.0 – 50.0 |
±1.00 |
±1.10 |
±1.20 |
|
50.0 – 60.0 |
±1.20 |
±1.30 |
±1.40 |
Width and Length Tolerances (Hot-Rolled – ASTM A480):
|
Width/Length Range |
Tolerance (mm) |
|
Width ≤1000mm |
+5.0 / -0.0 |
|
Width 1000-1500mm |
+6.0 / -0.0 |
|
Width 1500-2500mm |
+8.0 / -0.0 |
|
Length |
+10.0 / -0.0 |
Flatness Tolerances (Hot-Rolled – ASTM A480):
|
Thickness (mm) |
Width (mm) |
Flatness (mm per 1000mm) |
|
<6.0 |
≤1500 |
≤5mm |
|
6.0 – 12.0 |
≤1500 |
≤4mm |
|
12.0 – 25.0 |
≤2000 |
≤3mm |
|
>25.0 |
≤2000 |
≤2mm |
|
Surface Finish |
Code |
Description |
Typical Marine/HF Applications |
|
Annealed & Pickled |
No.1 |
Matte, rough surface from hot rolling followed by annealing and pickling. |
HF storage tanks, marine vessels |
|
Cold-Rolled, Pickled |
2D |
Dull, matte finish; non-reflective. |
Industrial fabrications, brine handling |
|
Cold-Rolled, Bright Annealed |
2B |
Bright, smooth, reflective finish. |
Marine components, desalination |
|
Bright Annealed (BA) |
BA |
Mirror-like finish from controlled atmosphere annealing. |
Naval degaussing components |
|
Passivated Finish |
— |
Surface chemically treated to enhance corrosion protection. |
Critical marine and HF service |
|
Polished (180-400 grit) |
No.4 |
Linear polished finish, brushed appearance. |
Decorative marine applications |
|
Finish |
Ra (μm) |
Application |
|
No.1 (Hot-rolled pickled) |
≤3.5 |
HF storage tanks |
|
2B (Cold-rolled bright) |
0.3 – 0.5 |
Marine components |
|
BA (Bright annealed) |
0.1 – 0.3 |
Naval degaussing systems |
|
No.4 (Polished) |
0.2 – 0.5 |
Decorative marine |
Monel 400 is inherently non-magnetic with magnetic permeability <1.005. For naval degaussing system components, Womic Steel offers magnetic permeability testing:
|
Parameter |
Specification |
|
Magnetic Permeability |
<1.005 at 200 Oe (15.9 kA/m) |
|
Test Method |
ASTM A342 |
|
Certification |
Permeability test report included upon request |
|
Application |
Mine countermeasure vessels, degaussing systems, submarine components |
Chemical Analysis: PMI 100% verification using handheld XRF spectrometer for Ni (≥63%), Cu (28-34%), Fe (≤2.5%).
Mechanical Testing: Tensile strength (≥480 MPa), yield strength (≥170 MPa), elongation (≥35%), hardness (≤180 HBW) per ASTM A370.
Non-Magnetic Verification: Magnetic permeability testing (<1.005) upon request.
Dimensional Inspection: Thickness, width, length, flatness, squareness using calibrated instruments.
Surface Inspection: Visual check for surface defects, cracks, laminations, and consistency.
Ultrasonic Testing (UT): Per ASTM A435 for internal flaw detection (upon request).
Intergranular Corrosion Test: ASTM G28 – upon request.
Sour Service Qualification (limited, upon request): HIC per NACE TM0284, SSC per NACE TM0177.
Third-Party Inspection: SGS, BV, DNV, ABS, TUV, LR on customer request.
HF Alkylation Units (Petrochemical Refining): Hydrofluoric acid (HF) storage
tank plates, acid cooler shells, regenerator column vessels, HF storage tank
linings, alkylate product vessels, acid settling drum shells (NACE MR0175
limited sour service).
Marine & Shipbuilding: Seawater cooling heat
exchanger plates, propulsion cooling water components, ballast water treatment
system vessels, fire main system plates, shipboard sanitary system tanks,
degaussing system structural plates (non-magnetic requirement) – ABS, BV, DNV,
LR, GL, RINA, CCS, KR, NK certified.
Naval Vessels (Military Applications): Non-magnetic plate components
for mine countermeasure vessels, submarine hydraulic system parts, degaussing
system structural elements, low-magnetic signature vessel components.
Desalination Plants: Brine heater plates, brine
preheater components, multi-stage flash (MSF) evaporator shells, high-velocity
brine handling vessels, chemical injection tanks.
Chemical Processing (Brine & Chlor-Alkali): Brine heater plates,
chlor-alkali plant brine tank linings, salt evaporator vessels, caustic service
tanks (deaerated conditions), sodium chloride brine handling equipment.
Offshore Platforms: Seawater intake plates,
firewater system tanks, cooling water heat exchanger shells, chemical injection
vessels (limited sour service, NORSOK M-650 qualified upon request).
Power Generation (Coastal): Seawater-cooled condenser
shells, auxiliary cooling water vessels, intake structure components.
Womic Steel offers precision cutting services for Monel 400 stainless steel plates:
|
Cutting Method |
Thickness Range |
Tolerances |
Applications |
|
Plasma Cutting |
5mm – 50mm |
±1.5mm |
Heavy plate profiling for HF vessels |
|
Laser Cutting |
3mm – 20mm |
±0.5mm |
Precision shapes, complex profiles |
|
Waterjet Cutting |
3mm – 50mm |
±0.5mm |
No heat-affected zone |
|
Shearing |
3mm – 12mm |
±1.0mm |
Square cuts, rectangles |
Standard Packaging:
Plates wrapped with moisture-proof paper and VCI film
Edge protectors to prevent damage
Steel skids or wooden pallets for plate protection
Clear labeling with grade (Monel 400/N04400), heat number, dimensions, weight, magnetic permeability (if tested)
Womic Steel's Shipping Strengths:
Direct cooperation with global shipowners – competitive freight rates
Professional loading and securing teams prevent plate bending and damage
Efficient document preparation (EN 10204 Type 3.1 MTR, PMI reports, marine classification certificates, non-magnetic test reports) minimizes customs delays
Rapid delivery time – standard plates maintained in ready stock
Continuous cargo tracking and after-sales follow-up
1. What is Monel 400 best suited for
in plate applications?
Monel 400 plates are primarily used for three key applications: (1)
Hydrofluoric acid (HF) alkylation vessels in refineries (premier material), (2)
High-velocity seawater handling equipment (excellent erosion resistance), and
(3) Non-magnetic naval vessel components where magnetic signature must be
minimized.
2. Can Monel 400 plates be used in
seawater applications?
Yes, excellent resistance. Monel 400 handles high-velocity seawater (up to 10
m/s) without impingement attack – significantly better than 316L, duplex, or
titanium. It also resists biofouling, reducing maintenance.
3. Is Monel 400 resistant to
hydrochloric acid (HCl)?
Limited. Monel 400 has fair resistance to deaerated dilute HCl but is not
recommended for concentrated or aerated HCl. For HCl service, Hastelloy C276 is
the preferred material.
4. What is the maximum temperature
for HF service?
Approximately 150°C (302°F). Above this temperature, other materials may be
required.
5. Why is Monel 400 non-magnetic?
Monel 400 has a nickel-copper austenitic structure that is inherently
non-magnetic with magnetic permeability <1.005. This property is critical
for degaussing systems on naval vessels.
6. Are Monel 400 plates available
with ASME certification?
Yes. Monel 400 plates can be supplied with ASME SB127 certification for
pressure vessel applications.
Premier HF Acid Material: Standard material for hydrofluoric acid alkylation vessels – proven in refineries worldwide
Excellent Seawater Resistance: Handles high-velocity seawater up to 10 m/s without erosion
Non-Magnetic for Naval Applications: Magnetic permeability <1.005 for degaussing systems
ASME SB127 Certified: Pressure vessel grade plates available
Marine Classification Certified: ABS, BV, DNV, LR approvals available
Full Traceability: Heat number on each plate – traceable to original mill certificate
Complete Size Range: Thickness from 3mm to 60mm – standard and custom sizes
Cut-to-Size Services: Plasma, laser, waterjet, and shearing for custom dimensions
Non-Magnetic Testing: Magnetic permeability verification upon request
Global Delivery: Exported to major marine, naval, and refinery projects worldwide
Tel / WhatsApp:
Victor: +86 15575100681
Jack: +86 18390957568
E-mail: info@womicstainless.com
Website: www.womicsteel.com
Contact Womic Steel today for a competitive quote on Monel 400 stainless steel plates. We offer certified quality, marine classification society certification, HF alkylation expertise, non-magnetic verification, ASME SB127 certification, and reliable global delivery for your marine, naval, and refinery projects.
Stock Examples (Hot-Rolled Monel 400 Plates – No.1 Finish – HF Service Grade):
|
Thickness |
Width |
Length |
Weight (approx) |
Primary Application |
|
6mm |
2000mm |
6000mm |
634 kg |
HF storage tank plates |
|
8mm |
2000mm |
6000mm |
845 kg |
Alkylation unit vessels |
|
10mm |
2000mm |
8000mm |
1409 kg |
Acid cooler shells |
|
12mm |
2000mm |
8000mm |
1691 kg |
Regenerator column vessels |
|
15mm |
2000mm |
8000mm |
2114 kg |
HF piping components |
|
20mm |
2000mm |
8000mm |
2819 kg |
Acid storage tanks |
|
25mm |
2500mm |
10000mm |
5500 kg |
Heavy HF vessels |
Stock Examples (Hot-Rolled Monel 400 Plates – No.1 Finish – Marine Grade):
|
Width |
Length |
Weight (approx) |
Primary Application |
|
|
6mm |
2000mm |
6000mm |
634 kg |
Marine heat exchanger shells |
|
8mm |
2000mm |
6000mm |
845 kg |
Seawater cooling components |
|
10mm |
2000mm |
8000mm |
1409 kg |
Shipboard piping plates |
|
12mm |
2000mm |
8000mm |
1691 kg |
Naval vessel components |
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