Womic Stainless Steel Co., Ltd

Duplex 2205 Stainless Steel Flanges

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Duplex 2205 Stainless Steel Flanges

High-Performance Duplex Flanges for Offshore Platforms, Seawater Systems, and Sour Gas Service

Premium Duplex 2205 (S31803/S32205) Stainless Steel Flanges for High-Strength, Chloride SCC Resistant, and High-Pressure Applications

Womic Steel manufactures premium Duplex 2205 Stainless Steel Flanges, covering a complete range of types including weld neck, slip-on, blind, socket weld, threaded, lap joint, and plate flanges. Our S31803/S32205 duplex flanges deliver approximately twice the yield strength of 316L (≥450 MPa) combined with excellent resistance to chloride stress corrosion cracking (SCC), outstanding pitting resistance, and exceptional performance in sour gas environments. They are the ideal choice for offshore platforms, seawater cooling systems, desalination plants, flue gas desulfurization (FGD) units, chemical processing vessels, and high-pressure oil and gas pipelines requiring NACE MR0175 compliance.

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Key Features of Duplex 2205 Stainless Steel Flanges

High Strength (≥450 MPa Yield): Approximately twice the yield strength of 316L, allowing for lighter schedules, reduced flange thickness, and significant weight savings in offshore and subsea applications.

Superior Chloride SCC Resistance: Outstanding resistance to chloride-induced stress corrosion cracking, performing reliably in high-chloride environments where .

Excellent Pitting and Crevice Corrosion Resistance: PRE (Pitting Resistance Equivalent) ≥ 34 for S31803 and ≥ 35 for S32205, providing reliable service in seawater, brackish water, and aggressive chemical media.

NACE MR0175 / ISO 15156 Compliant: Fully qualified for sour service (H₂S) applications up to 232°C (450°F), with documented HIC and SSC test reports available.

Good Weldability: Maintains balanced ferrite/austenite ratio (35–65% ferrite) when using proper welding procedures (low heat input, N₂ shielding gas). No post-weld heat treatment required for most applications.

Excellent Erosion and Corrosion Fatigue Resistance: Ideal for high-velocity seawater, slurry, and pump applications where combined mechanical and corrosive attack occurs.

Full Range of Types: Weld neck (WN), slip-on (SO), blind (BL), socket weld (SW), threaded (TH), lap joint (LJ), plate flanges, and orifice flanges.

Pressure Ratings: Available in Class 150, 300, 600, 900, 1500, and 2500 (PN6 to PN400 in metric equivalents).

Low Coefficient of Thermal Expansion: Lower than austenitic grades (13.5 μm/m·K vs 15.9 for 316L), reducing thermal stress in bolted flange connections.

International Certifications: Flanges can be certified by ABS, BV, DNV, LR, GL, RINA, CCS, KR, and NK, and comply with NORSOK M-630, NORSOK M-650, NACE MR0175, and ASME standards.

International Standards and Corresponding Grades for Duplex 2205 Flanges

Standard

Description

Corresponding Duplex Grade

ASME B16.5

Pipe flanges and flanged fittings (≤24″)

A182 F51 (S31803) / F60 (S32205)

ASME B16.47

Large diameter steel flanges (26″–60″) Series A/B

A182 F51 / F60

EN 1092-1

European standard flanges

1.4462 (X2CrNiMoN22-5-3)

JIS B2220

Japanese standard steel pipe flanges

SUS329J3L

GB/T 9112

Chinese national standard flanges

022Cr22Ni5Mo3N

MSS SP-44

Steel pipeline flanges

S31803 / S32205

NORSOK M-650

Offshore material qualification

Grade 2205

API 6A

Wellhead and Christmas tree flanges

S31803 / S32205

NACE MR0175 / ISO 15156

Sour service compliance

S31803 / S32205

These standards ensure that our Duplex 2205 stainless steel flanges meet global requirements for chemical composition, balanced dual-phase microstructure, mechanical properties, dimensional tolerances, and pressure-temperature ratings.

Chemical Composition of Duplex 2205 Flanges (S31803 / S32205)

Element

C

Mn

P

S

Si

Cr

Ni

Mo

N

S31803

≤0.030

≤2.00

≤0.030

≤0.020

≤1.00

21.0–23.0

4.5–6.5

2.5–3.5

0.08–0.20

S32205

≤0.030

≤2.00

≤0.030

≤0.020

≤1.00

22.0–23.0

4.5–6.5

3.0–3.5

0.14–0.20

S32205 is a restricted composition range of S31803, offering tighter control of Cr, Mo, and N to enhance corrosion resistance and ensure optimal phase balance. The addition of nitrogen promotes austenite stability and significantly increases pitting resistance. The PREN for S32205 is ≥35, compared to ≤24 for 316L.


Comparison of PREN (Pitting Resistance Equivalent) Values:

Grade

PRE

Seawater Suitability

304/304L

18–19

Poor

316/316L

24–26

Limited

Duplex 2205

≥35

Good to Excellent

Super Duplex 2507

≥42

Outstanding

Mechanical Properties and Heat Treatment Requirements

Property

Unit

S31803 / S32205 (Solution Annealed + Quenched)

Tensile Strength

MPa

≥620

Yield Strength (0.2% offset)

MPa

≥450

Elongation

%

≥25

Hardness (Brinell)

HBW

≤290

Hardness (Rockwell C)

HRC

≤30

Density

g/cm³

7.80

Melting Range

°C

1350–1400

Thermal Conductivity (20°C)

W/m·K

19.0

Coefficient of Thermal Expansion (20–100°C)

μm/m·K

13.5

Specific Heat Capacity (20°C)

J/kg·K

480

Impact Toughness (Charpy V-Notch, typical at -40°C):

Longitudinal: ≥ 60 J (typical)

NACE MR0175 / ISO 15156 Compliance:
Duplex 2205 is fully qualified for sour service applications up to 232°C (450°F) at H₂S partial pressures and pH levels defined in NACE MR0175/ISO 15156.


Maximum Recommended Service Temperatures:

Service Condition

Maximum Temperature

Continuous Service (Chloride Environment)

250°C (482°F)

Continuous Service (Non-Chloride Environment)

300°C (572°F)

Sour Service (NACE MR0175)

232°C (450°F)

Intermittent Service

325°C (617°F)

Critical Note: Duplex 2205 is not recommended for prolonged service above 300°C due to the risk of embrittling intermetallic phase precipitation (sigma phase).

Heat Treatment Condition:
All Duplex 2205 flanges are solution annealed at 1040–1120°C followed by rapid cooling (water quenching) . This heat treatment restores the balanced 40–60% ferrite / 40–60% austenite microstructure, dissolves unwanted intermetallic phases (sigma, chi), relieves internal stresses from forging, and ensures maximum corrosion resistance.

Critical Note: Unlike austenitic grades (304/316), Duplex 2205 requires water quenching after solution annealing. Air cooling is insufficient and will result in intermetallic phase precipitation, severely reducing corrosion resistance and toughness.

Delivery Condition: Flanges normally supplied in solution annealed and pickled condition, providing a clean, smooth surface and excellent corrosion resistance. Bright annealing is not recommended for duplex grades due to the water quenching requirement.

Pressure-Temperature Ratings for Duplex 2205 Flanges (per ASME B16.5)

Class

Rating (psig) @ 100°F

Rating (psig) @ 200°F

Rating (psig) @ 300°F

Rating (psig) @ 400°F

Rating (psig) @ 500°F

150

275

260

240

225

210

300

740

700

650

610

570

600

1480

1400

1300

1220

1140

900

2220

2100

1950

1830

1710

1500

3700

3500

3250

3050

2850

2500

6165

5830

5415

5080

4750

*Reference: Based on ASME B16.5 for duplex stainless steel (Group 2.2). De-rating factors at higher temperatures are more conservative than for austenitic grades due to risk of sigma phase embrittlement.*

Types and Production Range of Flanges from Womic Steel

Flange Type

Common Faces

Pressure Classes

Manufacturing Method

Typical Duplex Applications

Weld Neck (WN)

RF, RTJ, FF

150–2500

Forged + Machined

High-pressure offshore piping, wellhead connections

Slip-On (SO)

RF, FF

150–600

Forged + Machined

Low-to-medium pressure seawater systems

Blind (BL)

RF, RTJ, FF

150–2500

Forged + Machined

Pipeline closures, pressure vessel manways

Socket Weld (SW)

RF, FF

150–1500

Forged + Machined

Small bore, high-pressure instrumentation

Threaded (TH)

RF, FF

150–600

Forged + Machined

Non-welded connections, chemical injection

Lap Joint (LJ)

Flat face

150–600

Forged + Machined

Systems requiring frequent dismantling

Plate Flange

Flat face

150

Plate cutting + Machining

Low-pressure seawater intake

Orifice Flange

RF, RTJ

300–2500

Forged + Machined

Flow measurement in sour service pipelines

Dimensions and Manufacturing Range

Parameter

Weld Neck (WN)

Slip-On (SO)

Blind (BL)

Lap Joint (LJ)

Socket Weld (SW)

Nominal Size (DN/NPS)

1/2″ – 60″

1/2″ – 24″

1/2″ – 60″

1/2″ – 24″

1/2″ – 4″

Pressure Class

150 – 2500

150 – 600

150 – 2500

150 – 600

150 – 1500

Facing Types

RF, RTJ, FF, T&G, M&F

RF, FF

RF, RTJ, FF

Flat face

RF, FF

Hub Types

Long taper, short taper

Straight

N/A

Studded

Straight

Bore Types

Match pipe schedule

Slightly larger than pipe

N/A

Same as flange ID

Match pipe OD

Standard Dimensions: ASME B16.5 for sizes up to 24″, and ASME B16.47 Series A/B for large diameters up to 60″. EN 1092-1 dimensions available upon request.

Manufacturing Process of Duplex 2205 Stainless Steel Flanges

Raw Material Selection: High-quality S31803/S32205 duplex stainless steel bars or billets from certified mills (Outokumpu, Sandvik, POSCO, Baosteel) with certified chemical composition and ferrite/austenite balance. Raw material is NORSOK M-650 qualified and NACE MR0175 compliant.

Cutting & Heating: Material is cut to precise weight using band saws, then induction-heated to forging temperature (lower than austenitic grades, typically 1150–1200°C, to prevent ferrite coarsening).

Forging: Hot forged using hydraulic presses (3000–8000 tons) with strict temperature control. Multiple forging steps with careful reduction rates to maintain forgeability and prevent cracking.

Heat Treatment – Solution Annealing: Critical heat treatment at 1040–1120°C followed by immediate water quenching (<30 seconds delay) to restore balanced duplex microstructure and dissolve intermetallic phases.

Machining: CNC lathes and milling machines produce precise dimensions, bolt holes, and facing surfaces. Special tooling and slower cutting speeds are required due to higher strength of duplex.

Surface Finishing: Raised face serration, flat facing, or RTJ groove machining per ASME B16.5 requirements.

Ferrite Content Measurement: Verification of phase balance using magnetic induction or metallographic methods – requirement: 35–65% ferrite.

Marking: Laser engraving or stamping with grade (F51/F60/S31803/S32205), size (NPS), class, heat number, manufacturer identification, and standard.

Inspection & Testing: Dimensional check, PMI, ferrite measurement, hardness test, and NDT as required.

Surface Treatment: Pickling and passivation using specialized pickling acids optimized for duplex grades.

Surface Finishes for Duplex 2205 Flanges

Surface Finish

Description

Roughness (μinch)

Typical Duplex Application

Raised Face (RF)

Standard serrated concentric or spiral finish

125–250

Seawater piping, general process

Flat Face (FF)

Full face contact, smooth or serrated

125–250

Flat-faced equipment connections

Ring Type Joint (RTJ)

Grooved for oval or octagonal ring gasket

63 max

High-pressure sour gas service

Tongue & Groove (T&G)

Matched tongue and groove facing

125 min

Critical offshore connections

Male & Female (M&F)

Matched male/female facing

125 min

Subsea equipment connections

Pickled & Passivated

Chemically cleaned oxide-free surface

As machined

All duplex flange applications

Grit Blasted

Matte, uniform surface texture

Variable

Topside offshore (paint adhesion)

Each Duplex 2205 flange face is inspected for surface roughness, concentricity, and absence of defects.

Quality Control and Inspection

Chemical Analysis: PMI 100% verification using handheld XRF spectrometer for Cr, Ni, Mo, N.

Ferrite Content Measurement: Magnetic induction (ferritoscope) or metallographic method – requirement 35–65% ferrite.

Microstructure Examination: Verification of balanced dual-phase structure, absence of intermetallic phases (sigma, chi).

Mechanical Testing: Tensile strength (≥620 MPa), yield strength (≥450 MPa), elongation (≥25%), hardness (≤290 HBW).

Charpy Impact Testing: Per NORSOK M-630 at -46°C – ≥60J typical.

Dimensional Inspection: OD, ID, bolt circle, bolt hole alignment, thickness, flatness using calibrated gauges and CMM.

Thread Inspection: NPT thread verification using GO/NO-GO gauges per ANSI B1.20.1.

NDT – Liquid Penetrant Testing (PT): 100% for surface defects including cracks and forging laps.

NDT – Ultrasonic Testing (UT): For internal flaws upon request.

Corrosion Testing (upon request): ASTM G48 Method A pitting test (24 hours in 6% FeCl₃ at 40°C, no pitting required for NORSOK).

Intergranular Corrosion Test (IGC): ASTM A262 Practice E.

Sour Service Qualification (upon request): HIC per NACE TM0284, SSC per NACE TM0177.

NORSOK M-650 Qualification: Complete documentation package available.

Third-Party Inspection: SGS, BV, DNV, TUV, LR, or ABS on customer request.

Dimensional Tolerances (ASME B16.5 – Duplex 2205 Flanges)

Parameter

Size Range

Permitted Tolerance

Outside Diameter (OD)

≤4″ (DN100)

±1.6 mm

Outside Diameter (OD)

4″–8″ (DN100–DN200)

±2.4 mm

Outside Diameter (OD)

≥10″ (DN250)

±3.2 mm

Bolt Circle Diameter

All sizes

±0.8 mm

Bolt Hole Spacing

Adjacent holes

±0.5 mm

Bolt Hole Roundness

All sizes

±0.5 mm

Flange Thickness

All sizes

+3.0 mm / -0.0 mm

Hub Diameter

≤4″

±1.6 mm

Hub Diameter

≥6″

±2.4 mm

Hub Length (WN)

All sizes

±1.6 mm

Concentricity of RTJ groove

All sizes

±0.5 mm

RF Surface Roughness

All sizes

125–250 μinch

RF Height

All sizes

1.6 mm ±0.8 mm

Applications of Duplex 2205 Stainless Steel Flanges

Offshore Oil & Gas: Topside process piping, subsea manifold connections, riser flange joints, umbilical termination flanges, wellhead equipment (API 6A), Christmas tree flanges, choke and kill line connections (ABS, BV, DNV, LR certified, NACE MR0175 compliant).

Seawater Systems: Seawater cooling pipe flanges, firewater system flanges, ballast water treatment connections, offshore platform seawater lift pump flanges.

Desalination Plants: Brine heater flanges, high-pressure reverse osmosis feed line flanges, brine discharge flanges, multi-stage flash (MSF) evaporator connections.

Chemical Processing: Chloride-containing acid transfer flanges, pulp & paper bleach plant flanges, phosphoric acid and sulfuric acid process flanges.

Flue Gas Desulfurization (FGD): Absorber tower flanges, slurry piping flanges, reheat duct flanges, quench nozzle flanges.

Oil Refining: Sour water stripper flanges, amine regenerator flanges, hydrotreater feed/effluent flanges (NACE MR0175 compliant).

Marine Engineering: Shipboard seawater cooling flanges, ballast system flanges, desulfurization scrubber flanges (classification society certified).

Water Treatment: Brackish water reverse osmosis flanges, chemical injection flanges.

Power Generation: Coastal power plant cooling water flanges, FGD flanges, auxiliary cooling connections.

Packaging, Shipping, and Logistics

Small flanges (≤4″): Heavy-duty cartons with moisture barrier paper on pallets.
Medium flanges (6″–12″): Wooden crates with foam padding dividers, VCI paper wrapping.
Large flanges (≥14″): Individual wooden crates or steel-framed pallets with foam padding.


All shipments:

Rust preventive oil coating (optional – may be omitted for pickled finish).

Individual tagging: Grade (F51/F60), size, class, heat number, heat treatment condition, standard, PO number.

Waterproof shipping marks for export containers.


Womic Steel’s Delivery Strengths:

Ready stock: Class 150 and 300 Duplex 2205 flanges in sizes 1/2″–12″ – dispatch within 24 hours.

Direct cooperation with global shipowners for the most competitive freight rates.

Professional loading by in-house teams using padded slings to prevent surface damage.

Complete documentation for customs clearance including EN 10204 3.1 MTR, NORSOK M-650 documentation, NACE compliance certificates, ferrite measurement reports, and inspection certificates.

Continuous cargo tracking and after-sales follow-up.

Frequently Asked Questions (FAQ)

1. What is the difference between S31803 and S32205 Duplex 2205 flanges?
S32205 is a restricted composition range of S31803 with tighter controls on Cr (22.0–23.0%), Mo (3.0–3.5%), and N (0.14–0.20%). S32205 offers higher corrosion resistance (PRE ≥35 vs ≥34) and is generally preferred for new construction, especially in offshore and sour service applications.

2. Are Duplex 2205 flanges suitable for sour service (H₂S environments)?
Yes. Duplex 2205 is fully NACE MR0175 / ISO 15156 compliant for sour service up to 232°C (450°F). We can supply documented HIC and SSC test reports upon request.

3. Can Duplex 2205 flanges be welded to 316L piping?
Yes, but requires careful procedure with appropriate filler metal (typically 2209 or 309LMo). The transition should be designed to avoid galvanic corrosion, and welding procedures must be qualified.

4. What is the maximum service temperature for Duplex 2205 flanges?
250°C (482°F) for chloride service; 300°C (572°F) for non-chloride service. Above 300°C, risk of sigma phase embrittlement increases significantly. For higher temperatures, consider super duplex 2507 or austenitic grades.

5. Do Duplex 2205 flanges require post-weld heat treatment?
Generally, no. However, welding procedures must control heat input and interpass temperature. For maximum corrosion resistance in severe sour service, full solution annealing after welding may be specified.

6. What facing is recommended for high-pressure sour gas flanges?
Ring Type Joint (RTJ) facing with octagonal ring gasket is recommended for high-pressure sour gas service to ensure leak-tight sealing.

7. Can you supply Duplex 2205 flanges with NORSOK M-650 documentation?
Yes. We maintain NORSOK M-650 qualified material and can supply complete documentation packages including manufacturing procedure specification (MPS), procedure qualification record (PQR), and production test reports.

8. Are Duplex 2205 flanges available in EN 1092-1 dimensions?
Yes. We can manufacture Duplex 2205 flanges to EN 1092-1 Type 01, 02, 05, 11, 12 with PN6 to PN400 pressure ratings. Please specify your requirement.

Why Choose Womic Steel for Duplex 2205 Stainless Steel Flanges?

Complete Product Range: Weld neck, slip-on, blind, socket weld, threaded, lap joint, and plate flanges – one-stop purchasing for offshore and marine projects.

Strict Quality Control: ISO 9001:2015, PED 2014/68/EU, and API Q1 certified facilities.

NORSOK M-650 Qualified: Complete documentation packages available for offshore projects.

NACE MR0175 / ISO 15156 Compliant: Sour service certification with HIC/SSC test reports on request.

Advanced Forging & Machining: 3000–8000 ton hydraulic presses and CNC machining centers.

Full Traceability: Heat number stamped on each flange – traceable back to original mill certificate with ferrite measurement records.

Ferrite Content Control: 100% ferrite measurement (35–65% required) documented on test reports.

Flexible Customization: Special facing types (RTJ, T&G, M&F), custom bolt drilling, and non-standard sizes available.

Marine & Offshore Certified: ABS, BV, DNV, LR, GL, RINA certification available.

Global Delivery: Exported to major offshore projects worldwide including North Sea, Gulf of Mexico, Middle East, Southeast Asia, and Australia.

Contact Us

Tel / WhatsApp:
Victor: +86 15575100681
Jack: +86 18390957568

E-mail: info@womicstainless.com

Website: www.womicsteel.com

Contact Womic Steel today for a competitive quote on Duplex 2205 stainless steel flanges. We offer certified quality, NORSOK M-650 documentation, NACE MR0175 compliance, fast production lead times, and reliable global delivery to keep your offshore and marine projects running smoothly.

Appendix: Common Sizes & Related Keywords

Stock Examples (Class 150 WN RF – Duplex 2205):

NPS

DN

Schedule

Class

1/2″

15

Sch40S

150

2″

50

Sch40S

150

4″

100

Sch10S

150

6″

150

Sch40S

150

8″

200

Sch80S

150

10″

250

Sch40S

150

12″

300

Sch80S

150


Stock Examples (Class 300 WN RF – Duplex 2205):

NPS

DN

Schedule

Class

1/2″

15

Sch80S

300

1″

25

Sch40S

300

2″

50

Sch80S

300

4″

100

Sch40S

300

6″

150

Sch80S

300


Related Keywords (Duplex 2205 Flanges):

ASME B16.5 Duplex 2205 weld neck flange, S31803 slip on flange Class 150, S32205 blind flange RTJ, socket weld flange 3000LB Duplex 2205, threaded flange NPT Duplex stainless, lap joint flange stub end Duplex, EN 1092-1 1.4462 plate flange, NORSOK M-650 Duplex 2205 weld neck flange, NACE MR0175 Duplex blind flange, API 6A Duplex 2205 flange, A182 F51 weld neck flange, A182 F60 slip on flange, offshore Duplex 2205 RTJ flange, seawater resistant Duplex flange, sour service Duplex 2205 blind flange, high strength Duplex flange, ferrite controlled Duplex 2205 flange, ABS certified Duplex flange, DNV approved Duplex 2205 flange, CHOKE manifold Duplex flange, subsea Duplex 2205 flange, FGD Duplex flange, desalination Duplex flange, 2205 vs 316L flange selection, Duplex stainless steel flange weight chart, ferrite content testing Duplex flange, HIC tested Duplex 2205 flange, SSC tested Duplex flange, PREN 35 Duplex flange, 45K yield strength Duplex flange, duplex stainless flange chemical injection line, seawater lift pump Duplex flange.

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