Womic Stainless Steel Co., Ltd
Superior Sulfuric and Phosphoric Acid Resistance:
Outstanding performance in H₂SO₄ (all concentrations up to moderate temperature), H₃PO₄, and mixed acids – premier lined pipe material for fertilizer and chemical processing facilities.
NACE MR0175 / ISO 15156 Compliant:
Fully qualified for sour service (H₂S) up to 232°C (450°F), with documented HIC and SSC test reports available.
Excellent Chloride SCC Resistance:
High nickel content (38-46%) provides outstanding resistance to chloride-induced SCC, outperforming all austenitic and duplex stainless steel grades.
Good Pitting and Crevice Corrosion Resistance:
Molybdenum (2.5-3.5%) and chromium (19.5-23.5%) provide enhanced localized corrosion resistance.
Titanium Stabilization:
Titanium addition (0.6-1.2%) stabilizes the alloy against intergranular corrosion after welding – no PWHT required.
Cost-Effective Alternative to Solid Alloy 825:
Reduces material cost by 50-70% compared to solid Alloy 825 pipe while providing equivalent internal corrosion protection.
Excellent Resistance to Reducing and Oxidizing Acids:
Performs well in both reducing acids (sulfuric, hydrochloric, phosphoric) and oxidizing acids (nitric, chromic), as well as mixed acid environments.
Good High-Temperature Strength:
Maintains excellent mechanical properties up to 540°C (1000°F) in non-oxidizing environments.
Weldable End Preparation:
Available with weld overlay transition (butter layer) using matching filler metals at pipe ends.
Full Range of Sizes:
Available from 2″ to 48″ (DN50 to DN1200) with lining thickness from 2mm to 6mm.
International Certifications:
Lined pipes can be certified by ABS, BV, DNV, LR, and comply with NORSOK M-650, NACE MR0175, and ASME standards.
|
Standard |
Description |
Base Pipe Grade |
Lining Grade |
|
ASTM A106 |
Seamless carbon steel pipe for high-temperature service |
Grade B |
UNS N08825 |
|
API 5L |
Line pipe for oil and gas |
Gr B, X42, X52, X60, X65 |
UNS N08825 |
|
ASTM A333 |
Low-temperature carbon steel pipe |
Grade 6 |
UNS N08825 |
|
ASME B31.3 |
Process piping |
Various |
UNS N08825 |
|
ASTM A335 |
Alloy steel pipe for high-temperature service |
P11, P22 |
UNS N08825 |
|
NORSOK M-650 |
Offshore material qualification |
Various |
Alloy 825 |
|
NACE MR0175 / ISO 15156 |
Sour service compliance |
Various (hardness controlled) |
Alloy 825 |
|
EN 10216-5 |
Seamless steel tubes for pressure purposes |
P235GH, P265GH |
2.4858 |
|
Element |
Ni |
Cr |
Fe |
Mo |
Cu |
Ti |
C |
Mn |
P |
S |
Si |
Al |
|
Alloy 825 |
38.0–46.0 |
19.5–23.5 |
≥22.0 |
2.5–3.5 |
1.5–3.0 |
0.6–1.2 |
≤0.05 |
≤1.0 |
≤0.03 |
≤0.03 |
≤0.5 |
≤0.2 |
Alloy 825 is a nickel-iron-chromium alloy with controlled additions of molybdenum and copper for enhanced corrosion resistance in sulfuric acid service. The copper content (1.5-3.0%) provides exceptional resistance to sulfuric acid, while molybdenum (2.5-3.5%) enhances pitting resistance. Titanium stabilization prevents sensitization and intergranular corrosion after welding.
Comparison of Acid Resistance for Lining Materials:
|
Lining Grade |
Nickel (%) |
Copper (%) |
Sulfuric Acid (H₂SO₄) |
Phosphoric Acid (H₃PO₄) |
Sour Gas (H₂S) |
Cost vs Solid |
|
316/316L |
10-14 |
— |
Poor |
Fair |
Poor |
Low |
|
Duplex 2205 |
4.5-6.5 |
— |
Good |
Good |
Good |
Medium |
|
Super Duplex 2507 |
6-8 |
— |
Good |
Good |
Excellent |
High |
|
Alloy 825 |
38-46 |
1.5-3.0 |
Excellent |
Excellent |
Excellent |
**Medium-High |
|
Component |
Material |
Tensile Strength (MPa) |
Yield Strength (MPa) |
Elongation (%) |
|
Base Pipe (API 5L X52) |
Carbon Steel |
≥455 |
≥360 |
≥21 |
|
Base Pipe (A106 Gr B) |
Carbon Steel |
≥415 |
≥240 |
≥21 |
|
Base Pipe (A333 Gr 6) |
Low-Temp CS |
≥415 |
≥240 |
≥22 |
|
Lining (Alloy 825) |
Nickel Alloy |
≥585 |
≥240 |
≥30 |
|
Lining (Titanium Stabilized) |
Nickel Alloy |
≥585 |
≥240 |
≥30 |
|
Parameter |
Seamless Base Pipe |
Welded (SAW) Base Pipe |
|
Pipe Size Range |
2″ – 24″ (DN50 – DN600) |
8″ – 48″ (DN200 – DN1200) |
|
Base Pipe Wall Thickness |
Sch 40 – Sch 160 |
Sch 20 – Sch 80 |
|
Lining Thickness |
2mm – 6mm |
2mm – 6mm |
|
Standard Lengths |
6m, 12m |
6m, 12m |
|
End Preparation |
Beveled, Weld Overlay |
Beveled, Weld Overlay |
|
Base Pipe Grades |
API 5L X42-X65, A106 Gr B, A333 Gr 6, A335 P11/P22 |
API 5L X42-X65, A53 Gr B |
|
Service Severity |
Lining Thickness (mm) |
Recommended for |
|
Dilute Sulfuric Acid (≤50%) |
2.5mm – 3.0mm |
Acid transfer lines |
|
Concentrated Sulfuric Acid (93-98%) |
3.0mm – 4.0mm |
Acid cooler piping |
|
Phosphoric Acid Service |
2.5mm – 3.5mm |
Fertilizer production lines |
|
Mixed Acids (H₂SO₄/HNO₃) |
3.5mm – 5.0mm |
Pickling plant piping |
|
Sour Service (H₂S with chlorides) |
3.0mm – 4.0mm |
Sour gas pipelines (NACE) |
|
Hydrochloric Acid (Dilute) |
4.0mm – 6.0mm |
Acid regeneration lines |
Base Pipe Selection:
Carbon steel, low-temperature steel, or alloy steel base pipe selected based on service pressure, temperature, and mechanical requirements.
Base Pipe Preparation:
Base pipe is cleaned (shot blasting to SA 2.5), inspected, and prepared for lining application.
Lining Tube Fabrication:
Alloy 825 nickel alloy sheet is rolled and welded into a tube slightly smaller than the base pipe ID using matching filler metal (ERNiCrMo-3 or ERNiCrMo-10).
Lining Insertion:
The Alloy 825 lining tube is inserted into the base pipe.
Hydraulic Expansion:
High-pressure water (up to 5000 psi) expands the lining tube against the base pipe inner wall, creating a tight mechanical bond.
Solution Annealing:
Lining material is in solution annealed condition (925–1040°C) for optimal corrosion resistance.
Titanium Stabilization Verification:
ASTM G28 intergranular corrosion test performed to verify stabilization.
Weld Overlay (Butter Layer):
Pipe ends are prepared with Alloy 825 weld overlay using ERNiCrMo-3 or ERNiCrMo-10 filler metal.
Hydrostatic Testing:
Each lined pipe is hydrostatically tested to verify bond integrity and pressure rating.
NDT Inspection:
Ultrasonic testing (UT) and eddy current testing (ECT) verify lining thickness and bond quality.
End Finishing:
Pipe ends are beveled per ASME B16.25 and prepared for field welding.
Marking & Coating:
Pipes are marked with grade, size, lining thickness, heat number, and standard. External coating applied upon request.
|
Parameter |
Requirement |
|
Weld Overlay Material |
ERNiCrMo-3 (Alloy 625) or ERNiCrMo-10 |
|
Overlay Thickness |
3mm – 5mm (minimum) |
|
Overlay Length |
50mm – 100mm from pipe end |
|
Overlay Application |
GTAW (TIG) or GMAW (MIG) |
|
Interpass Temperature |
≤150°C |
|
Heat Treatment |
Not required (PWHT not necessary for Alloy 825) |
|
Preheating |
100-150°C for carbon steel base |
Base Pipe Inspection:
Chemical analysis, mechanical testing, dimensional check, hardness test.
Lining Material Verification:
PMI 100% for Alloy 825 lining material – verification of Ni (38-46%), Cr (19.5-23.5%), Mo (2.5-3.5%), Cu (1.5-3.0%), Ti (0.6-1.2%).
Intergranular Corrosion Test:
ASTM G28 – validates resistance to intergranular corrosion (mandatory for stabilized grades).
Bond Integrity Testing:
Ultrasonic test (UT) to verify bond between lining and base pipe – 100% coverage.
Lining Thickness Check:
Ultrasonic thickness measurement at multiple points.
Hydrostatic Test:
Each pipe tested at 1.5× design pressure.
Surface Inspection:
Internal and external surface inspection.
Dimensional Check:
OD, ID, wall thickness, length, straightness.
Sour Service Qualification (upon request):
HIC per NACE TM0284, SSC per NACE TM0177.
Third-Party Inspection:
SGS, BV, DNV, TUV, LR, ABS available.
Sulfuric Acid Plants:
Sulfuric acid transfer lines, acid cooler piping, oleum lines, spent acid recovery lines, acid storage tank connections.
Phosphoric Acid Production:
Wet-process phosphoric acid (WPA) transfer lines, evaporator inlet/outlet piping, reaction vessel connections, gypsum slurry lines.
Pickling Plants (Stainless Steel):
Pickling acid lines, acid recovery system piping, spent acid transfer lines, rinse water return lines.
Offshore Chemical Injection:
Methanol injection lines, glycol injection piping, MEG (monoethylene glycol) transfer lines (NORSOK M-650 qualified).
Sour Gas Service (H₂S):
Amine regenerator piping, sour water stripper lines, glycol dehydration unit piping (NACE MR0175 compliant).
Fertilizer Production:
DAP/MAP (diammonium phosphate/monoammonium phosphate) slurry lines, phosphoric acid feed lines.
Oil & Gas Produced Water:
Produced water transfer lines, water injection piping, separation vessel connections.
Hydrometallurgy:
Solvent extraction (SX) piping, electrowinning solution transfer lines, pregnant leach solution (PLS) lines.
Pharmaceutical:
High-purity acid transfer lines, API reactor connections, sterile process piping.
Heat Exchanger Interconnecting Piping:
Connecting piping for acid service heat exchangers.
|
Pipe Type |
4″ Sch 40 |
8″ Sch 40 |
16″ Sch 30 |
24″ Sch 20 |
|
Solid Alloy 825 Pipe |
100% (baseline) |
100% (baseline) |
100% (baseline) |
100% (baseline) |
|
Lined Pipe (CS + 3mm Alloy 825) |
30-40% |
25-35% |
20-30% |
15-25% |
|
Cost Savings |
60-70% |
65-75% |
70-80% |
75-85% |
|
Requirement |
Alloy 825 Lined Pipe Compliance |
|
Lining Material |
Alloy 825 (UNS N08825) – Fully Compliant |
|
Base Pipe Hardness |
≤22 HRC (carbon steel) – Controlled |
|
Weld Overlay (Butter) |
ERNiCrMo-3 – Hardness ≤35 HRC |
|
Maximum H₂S Partial Pressure |
High (nickel-based alloy limits) |
|
Maximum Temperature |
232°C (450°F) |
|
HIC Test (NACE TM0284) |
Available upon request |
|
SSC Test (NACE TM0177) |
Available upon request |
1. How does Alloy 825 lined pipe
compare to 316L lined pipe for acid service?
Alloy 825 lined pipe offers significantly better resistance to sulfuric acid
(H₂SO₄), phosphoric acid (H₃PO₄), and sour gas (H₂S). For acid plant piping
where 316L would corrode rapidly, Alloy 825 lined pipe is required. The cost
premium over 316L lined pipe is justified by the extended service life in
aggressive acid environments.
2. Is Alloy 825 resistant to
hydrochloric acid (HCl)?
Limited. Alloy 825 has fair resistance to dilute HCl but is not recommended for
concentrated or aerated HCl. For hydrochloric acid service, consider Hastelloy
C276 lined pipes.
3. Can Alloy 825 lined pipes be
welded in the field?
Yes, with proper weld overlay (buttering) at pipe ends using ERNiCrMo-3 (Alloy
625) filler metal. Titanium stabilization eliminates the need for PWHT.
Qualified welding procedures are available.
4. What is the maximum service
temperature for Alloy 825 lined pipes?
400°C (752°F) for general corrosive service. For sulfuric acid service
specifically, limit to 150°C (302°F) depending on acid concentration. Base pipe
can handle higher temperatures with appropriate material selection.
5. Are Alloy 825 lined pipes
suitable for sour service (H₂S)?
Yes, with proper hardness control. Alloy 825 lined pipes can be NACE MR0175 /
ISO 15156 compliant for sour service. HIC and SSC test reports available upon
request.
6. What base pipe material is
recommended for high-temperature acid service?
ASTM A335 Grade P11 (1.25Cr-0.5Mo) or P22 (2.25Cr-1Mo) is recommended for
high-temperature acid service where base pipe temperatures exceed 400°C.
Premier Acid Service Material:
Excellent resistance to H₂SO₄, H₃PO₄, and sour gas – ideal for chemical processing and fertilizer production
NACE MR0175 / ISO 15156 Compliant:
Full sour service documentation
Titanium Stabilized:
ASTM G28 intergranular corrosion tested – no PWHT required
Cost-Effective:
60-80% cost savings compared to solid Alloy 825 pipe
Full Traceability:
Heat number on each pipe – traceable to original mill certificate
Complete Size Range:
2″ to 48″ (DN50 to DN1200) – standard and custom sizes
Multiple Base Pipe Grades:
API 5L X42-X65, A106 Gr B, A333 Gr 6, A335 P11/P22
Lining Thickness Options:
2mm to 6mm – tailored to your acid concentration and temperature
Weld Overlay Ready:
Pipe ends prepared with ERNiCrMo-3 butter layer for field welding
NORSOK M-650 Qualified:
Complete offshore documentation packages
Third-Party Inspection:
SGS, BV, DNV, TUV, LR, ABS available
Global Delivery:
Exported to major chemical plants, acid facilities, and offshore projects worldwide
Website: www.womicstainless.com
E-mail: info@womicstainless.com
Tel / WhatsApp / WeChat:
Victor: +86 15575100681
Jack: +86 18390957568
Womic Steel – Your reliable partner for high‑quality stainless steel products, precision machined components, and custom solutions for corrosion‑resistant applications.
Stock Examples (Alloy 825 Lined Pipes – A106 Gr B Base – 3mm Lining – Weld Overlay Ends – Acid Service):
|
NPS |
DN |
Base Pipe Schedule |
Lining Thickness |
Base Pipe Grade |
Typical Application |
|
2″ |
50 |
Sch 80 |
3mm |
A106 Gr B |
Sulfuric acid transfer |
|
3″ |
80 |
Sch 80 |
3mm |
A106 Gr B |
Acid dosing lines |
|
4″ |
100 |
Sch 40 |
3mm |
A106 Gr B |
Phosphoric acid feed |
|
6″ |
150 |
Sch 40 |
3mm |
A106 Gr B |
Acid cooler piping |
|
8″ |
200 |
Sch 40 |
4mm |
A106 Gr B |
Pickling plant acid lines |
|
10″ |
250 |
Sch 40 |
4mm |
API 5L X52 |
Fertilizer slurry lines |
|
12″ |
300 |
Sch 30 |
4mm |
API 5L X52 |
Acid transfer main |
|
16″ |
400 |
Sch 30 |
5mm |
A106 Gr B |
Acid storage feed |
|
20″ |
500 |
Sch 20 |
5mm |
API 5L X52 |
Mixed acid pipelines |
|
24″ |
600 |
Sch 20 |
6mm |
A106 Gr B |
Phosphoric acid main |
Stock Examples (Alloy 825 Lined Pipes – API 5L X52 Base – 4mm Lining – Weld Overlay Ends – NACE MR0175 – Sour Gas Service):
|
NPS |
DN |
Base Pipe Schedule |
Lining Thickness |
Base Pipe Grade |
Typical Application |
|
4″ |
100 |
Sch 80 |
4mm |
API 5L X52 |
Sour gas gathering lines |
|
6″ |
150 |
Sch 80 |
4mm |
API 5L X52 |
Amine regenerator piping |
|
8″ |
200 |
Sch 60 |
5mm |
API 5L X52 |
Sour water stripper lines |
|
10″ |
250 |
Sch 60 |
5mm |
API 5L X65 |
HP sour gas pipelines |
Stock Examples (Alloy 825 Lined Pipes – A333 Gr 6 Base – Low Temperature – 4mm Lining – Arctic Sour Service):
|
DN |
Base Pipe Schedule |
Lining Thickness |
Base Pipe Grade |
Typical Application |
|
|
6″ |
150 |
Sch 80 |
4mm |
A333 Gr 6 |
Arctic sour gas gathering |
|
8″ |
200 |
Sch 80 |
4mm |
A333 Gr 6 |
Low-temperature acid service |
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